We can implement a simple sign-up form using python as shown below:

import tkinter as tk

class SignupForm(tk.Frame):
    def __init__(self, master=None):
        super().__init__(master)
        self.master = master
        self.master.title("Signup Form")
        self.pack()

        # creating form labels and fields
        self.name_label = tk.Label(self, text="Name:")
        self.name_label.grid(row=0, column=0)
        self.name_entry = tk.Entry(self)
        self.name_entry.grid(row=0, column=1)

        self.email_label = tk.Label(self, text="Email:")
        self.email_label.grid(row=1, column=0)
        self.email_entry = tk.Entry(self)
        self.email_entry.grid(row=1, column=1)

        self.password_label = tk.Label(self, text="Password:")
        self.password_label.grid(row=2, column=0)
        self.password_entry = tk.Entry(self, show="*")
        self.password_entry.grid(row=2, column=1)

        # creating submit button
        self.submit_button = tk.Button(self, text="Submit", command=self.submit)
        self.submit_button.grid(row=3, column=1)

    def submit(self):
        # receive form data
        name = self.name_entry.get()
        email = self.email_entry.get()
        password = self.password_entry.get()

        # printing the form data to the console
        print("Name:", name)
        print("Email:", email)
        print("Password:", password)

root = tk.Tk()
app = SignupForm(master=root)
app.mainloop()

This code creates a simple signup form with three fields: name, email, and password. The form is created using the tkinter.Frame class and the various form fields are added using the tkinter.Label and tkinter. Entry classes. A submit button is also created using the tkinter.Button class, which calls the submit() method when clicked. The submit() method retrieves the data from the form fields using the get() method, and then prints the data to the console.

To run this code, save it to a file (e.g. signup_form.py) and run it from the command line using python signup_form.py. A window will appear with the signup form, and you can enter data into the form fields and click the Submit button to see the data printed to the console.